Not entirely sure. I just had the lyric "but he was mean and he was coarse and unrefined" stuck in my head when I read the question and I think Shang is probably the closest to that description out of the Princes. Also "She glanced this way, I thought I saw.." -- she stares at him often because of his sexy body, hah, and "Who'd have ever thought that this could be??" - I doubt she would've thought romance would be her priority before she enlisted to the army. Also by the end they're the best of friends!

But anyway, I'll stop babbling.

or Tiana or Jasmine....

And Jasmine and Mulan